Synthesis, structures, and electroluminescent properties of scandium N,O-chelated complexes toward near-white organic light-emitting diodes.
Identifieur interne : 001701 ( Main/Exploration ); précédent : 001700; suivant : 001702Synthesis, structures, and electroluminescent properties of scandium N,O-chelated complexes toward near-white organic light-emitting diodes.
Auteurs : RBID : pubmed:20423054English descriptors
- KwdEn :
- MESH :
- chemical , chemical synthesis : Chelating Agents, Organometallic Compounds.
- chemical , chemistry : Chelating Agents, Organometallic Compounds, Scandium.
- Computer Simulation, Crystallography, X-Ray, Electrochemistry, Light, Luminescence, Models, Molecular, Molecular Structure.
Abstract
Three members of a new class of electroluminescent, neutral, and monomeric scandium N,O-chelate complexes, namely, Sc(III)-tris-2-(2-benzoimidazol-2-yl)phenolate (1), Sc(III)-tris-2-(2-benzoxyazol-2-yl)phenolate (2), and Sc(III)-tris-2-(2-benzothiazol-2-yl)phenolate (3), have been prepared and X-ray characterized. DFT calculations have been performed. In contrast to the most frequently applied dual or multiple dopants in multilayer white OLED devices, all our simpler devices with the configuration of indium tin oxide/N,N'-bis(3-methylphenyl)-N,N'-diphenylbenzidine/neat scandium complex/Yb exhibit close to near-white emission with a blue hue (CIE(x,y) = 0.2147, 0.2379) in the case of 1, a cyan hue (0.2702, 0.3524) in the case of 2, and a yellowish hue (0.3468; 0.4284) in the case of 3.
DOI: 10.1021/ic1002429
PubMed: 20423054
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Synthesis, structures, and electroluminescent properties of scandium N,O-chelated complexes toward near-white organic light-emitting diodes.</title><author><name sortKey="Katkova, Marina A" uniqKey="Katkova M">Marina A Katkova</name><affiliation wicri:level="1"><nlm:affiliation>G.A. Razuvaev Institute of Organometallic Chemistry of RAS, Tropinina 49, Nizhny Novgorod, 603950, Russia.</nlm:affiliation><country xml:lang="fr">Russie</country><wicri:regionArea>G.A. Razuvaev Institute of Organometallic Chemistry of RAS, Tropinina 49, Nizhny Novgorod, 603950</wicri:regionArea></affiliation></author><author><name sortKey="Balashova, Tatyana V" uniqKey="Balashova T">Tatyana V Balashova</name></author><author><name sortKey="Ilichev, Vasilii A" uniqKey="Ilichev V">Vasilii A Ilichev</name></author><author><name sortKey="Konev, Alexey N" uniqKey="Konev A">Alexey N Konev</name></author><author><name sortKey="Isachenkov, Nikolai A" uniqKey="Isachenkov N">Nikolai A Isachenkov</name></author><author><name sortKey="Fukin, Georgy K" uniqKey="Fukin G">Georgy K Fukin</name></author><author><name sortKey="Ketkov, Sergey Yu" uniqKey="Ketkov S">Sergey Yu Ketkov</name></author><author><name sortKey="Bochkarev, Mikhail N" uniqKey="Bochkarev M">Mikhail N Bochkarev</name></author></titleStmt><publicationStmt><date when="2010">2010</date><idno type="doi">10.1021/ic1002429</idno><idno type="RBID">pubmed:20423054</idno><idno type="pmid">20423054</idno><idno type="wicri:Area/Main/Corpus">001955</idno><idno type="wicri:Area/Main/Curation">001955</idno><idno type="wicri:Area/Main/Exploration">001701</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chelating Agents (chemical synthesis)</term><term>Chelating Agents (chemistry)</term><term>Computer Simulation</term><term>Crystallography, X-Ray</term><term>Electrochemistry</term><term>Light</term><term>Luminescence</term><term>Models, Molecular</term><term>Molecular Structure</term><term>Organometallic Compounds (chemical synthesis)</term><term>Organometallic Compounds (chemistry)</term><term>Scandium (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemical synthesis" xml:lang="en"><term>Chelating Agents</term><term>Organometallic Compounds</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Chelating Agents</term><term>Organometallic Compounds</term><term>Scandium</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Computer Simulation</term><term>Crystallography, X-Ray</term><term>Electrochemistry</term><term>Light</term><term>Luminescence</term><term>Models, Molecular</term><term>Molecular Structure</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Three members of a new class of electroluminescent, neutral, and monomeric scandium N,O-chelate complexes, namely, Sc(III)-tris-2-(2-benzoimidazol-2-yl)phenolate (1), Sc(III)-tris-2-(2-benzoxyazol-2-yl)phenolate (2), and Sc(III)-tris-2-(2-benzothiazol-2-yl)phenolate (3), have been prepared and X-ray characterized. DFT calculations have been performed. In contrast to the most frequently applied dual or multiple dopants in multilayer white OLED devices, all our simpler devices with the configuration of indium tin oxide/N,N'-bis(3-methylphenyl)-N,N'-diphenylbenzidine/neat scandium complex/Yb exhibit close to near-white emission with a blue hue (CIE(x,y) = 0.2147, 0.2379) in the case of 1, a cyan hue (0.2702, 0.3524) in the case of 2, and a yellowish hue (0.3468; 0.4284) in the case of 3.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">20423054</PMID><DateCreated><Year>2010</Year><Month>06</Month><Day>01</Day></DateCreated><DateCompleted><Year>2010</Year><Month>09</Month><Day>01</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1520-510X</ISSN><JournalIssue CitedMedium="Internet"><Volume>49</Volume><Issue>11</Issue><PubDate><Year>2010</Year><Month>Jun</Month><Day>7</Day></PubDate></JournalIssue><Title>Inorganic chemistry</Title><ISOAbbreviation>Inorg Chem</ISOAbbreviation></Journal><ArticleTitle>Synthesis, structures, and electroluminescent properties of scandium N,O-chelated complexes toward near-white organic light-emitting diodes.</ArticleTitle><Pagination><MedlinePgn>5094-100</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/ic1002429</ELocationID><Abstract><AbstractText>Three members of a new class of electroluminescent, neutral, and monomeric scandium N,O-chelate complexes, namely, Sc(III)-tris-2-(2-benzoimidazol-2-yl)phenolate (1), Sc(III)-tris-2-(2-benzoxyazol-2-yl)phenolate (2), and Sc(III)-tris-2-(2-benzothiazol-2-yl)phenolate (3), have been prepared and X-ray characterized. DFT calculations have been performed. In contrast to the most frequently applied dual or multiple dopants in multilayer white OLED devices, all our simpler devices with the configuration of indium tin oxide/N,N'-bis(3-methylphenyl)-N,N'-diphenylbenzidine/neat scandium complex/Yb exhibit close to near-white emission with a blue hue (CIE(x,y) = 0.2147, 0.2379) in the case of 1, a cyan hue (0.2702, 0.3524) in the case of 2, and a yellowish hue (0.3468; 0.4284) in the case of 3.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Katkova</LastName><ForeName>Marina A</ForeName><Initials>MA</Initials><Affiliation>G.A. Razuvaev Institute of Organometallic Chemistry of RAS, Tropinina 49, Nizhny Novgorod, 603950, Russia.</Affiliation></Author><Author ValidYN="Y"><LastName>Balashova</LastName><ForeName>Tatyana V</ForeName><Initials>TV</Initials></Author><Author ValidYN="Y"><LastName>Ilichev</LastName><ForeName>Vasilii A</ForeName><Initials>VA</Initials></Author><Author ValidYN="Y"><LastName>Konev</LastName><ForeName>Alexey N</ForeName><Initials>AN</Initials></Author><Author ValidYN="Y"><LastName>Isachenkov</LastName><ForeName>Nikolai A</ForeName><Initials>NA</Initials></Author><Author ValidYN="Y"><LastName>Fukin</LastName><ForeName>Georgy K</ForeName><Initials>GK</Initials></Author><Author ValidYN="Y"><LastName>Ketkov</LastName><ForeName>Sergey Yu</ForeName><Initials>SY</Initials></Author><Author ValidYN="Y"><LastName>Bochkarev</LastName><ForeName>Mikhail N</ForeName><Initials>MN</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType><PublicationType>Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Inorg Chem</MedlineTA><NlmUniqueID>0366543</NlmUniqueID><ISSNLinking>0020-1669</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Chelating Agents</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Organometallic Compounds</NameOfSubstance></Chemical><Chemical><RegistryNumber>YUJ4U1EW7R</RegistryNumber><NameOfSubstance>Scandium</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Chelating Agents</DescriptorName><QualifierName MajorTopicYN="Y">chemical synthesis</QualifierName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Computer Simulation</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Crystallography, X-Ray</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Electrochemistry</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Light</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y">Luminescence</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Models, Molecular</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Molecular Structure</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Organometallic Compounds</DescriptorName><QualifierName MajorTopicYN="Y">chemical synthesis</QualifierName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Scandium</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2010</Year><Month>4</Month><Day>29</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2010</Year><Month>4</Month><Day>29</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2010</Year><Month>9</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1021/ic1002429</ArticleId><ArticleId IdType="pubmed">20423054</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=IndiumV2/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001701 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001701 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= *** parameter Area/wikiCode missing ***
|area= IndiumV2
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:20423054
|texte= Synthesis, structures, and electroluminescent properties of scandium N,O-chelated complexes toward near-white organic light-emitting diodes.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:20423054" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a IndiumV2
| This area was generated with Dilib version V0.5.76. |  |